Short-term and interannual variability of redox-sensitive chemical parameters in hypoxic/anoxic bottom waters of the Chesapeake Bay     

Brent L. Lewis  Brian T. Glazer  Paul J. Montbriand  George W. Luther III  Donald B. Nuzzio  Timothy Deering  Shufen Ma  Stephen Theberge 《Marine Chemistry》2007,105(3-4):296-308

A combination of CTD casts, discrete bottle sampling and in situ voltammetric microelectrode profiling was used to examine changing redox conditions in the water column at a single station south of the Bay Bridge in the upper Chesapeake Bay in late July/early August, 2002–2005. Short-term (2–4 h) fluctuations in the oxic/suboxic/anoxic interface were documented using in situ voltammetric solid-state electrodes. Profiles of dissolved oxygen and sulfide revealed tidally-driven vertical fluctuations of several meters in the depth and thickness of the suboxic zone. Bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ also varied over the tidal cycle by approximately an order of magnitude. These data indicate that redox species concentrations at this site varied more due to physical processes than biogeochemical processes. Based on analysis of ADCP data, tidal currents at this station were strongly polarized, with the principal axis of tidal currents aligned with the mainstem channel. Together with the chemical data, the ADCP analysis suggests tidal flushing of anoxic bottom waters with suboxic water from north of the site. The present study is thus unique because while most previous studies have focused on processes across relatively stable redox interfaces, our data clearly demonstrate the influence of rapidly changing physical mixing processes on water column redox chemistry.Also noted during the study were interannual differences in maximum bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺. In 2003, for example, heavy spring rains resulted in severe hypoxia/anoxia in June and early July. While reported storm-induced mixing in late July/early August 2003 partially alleviated the low-oxygen conditions, bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ were still much higher than in the previous year. The latter implies that the response time of the microbial community inhabiting the suboxic/anoxic bottom waters to changing redox conditions is slow compared to the time scale of episodic mixing events. Bottom water concentrations of the redox-sensitive chemical species should thus be useful as a tracer to infer prior hypoxic/anoxic conditions not apparent from ambient oxygen levels at the time of sampling.  相似文献   

Effort distribution and catch patterns adjacent to temperate MPAs   总被引：7，自引：2，他引：7  

Murawski  Steven A.; Wigley  Susan E.; Fogarty  Michael J.; Rago  Paul J.; Mountain  David G. 《ICES Journal of Marine Science》2005,62(6):1150-1167

  相似文献   

Petroleum geochemistry of the Kimmeridge Clay of onshore Southern and Eastern England     

Paul F. V. Williams 《Marine and Petroleum Geology》1986,3(4)

The Kimmeridge Clay is considered a major oil source rock for the North Sea hydrocarbon province. The formation is also developed onshore in an organic-rich mudstone facies. This paper examines the possibility of onshore oil generation from the Kimmeridge Clay. Geochemically, onshore basin margin sediments contain rich, potential source horizons with mainly Type l/Type ll oil-prone kerogen, but are immature. Some deeper Cleveland Basin sediments have reached marginal maturity. Burial history reconstruction suggests significant formation palaeoburial depths in central areas of the Cleveland and Wessex Basins. Computed vitrinite isoreflectance contours show the Wealden and Isle of Wight Kimmeridge Clay to be thermally mature. Basin modelling suggests an early Palaeogene onset of oil generation in parts of the Cleveland Basin, while maximum oil generation could have been reached by the formation base in the Isle of Wight area during the late Cretaceous. Although basin subsidence ceased in the Neogene, in the Weald and Isle of Wight, where the formation is still deeply buried, oil generation probably continued for some time during uplift. Thus significant quantities of oil could have been generated. Whether or not this oil is present today however, would depend on the correct timing of suitable migration and trap structures.  相似文献   

North Pacific Synthesis of the Joint Global Ocean Flux Study: Overview     

Toshiro Saino  Alexander Bychkov  Chen-Tung Arthur Chen  Paul J. Harrison 《Journal of Oceanography》2004,60(1):1-4

This special issue is comprised of 13 papers, including this overview, and focuses on the synthesis of the Joint Global Ocean Flux Study (JGOFS) in the North Pacific which took place from 1997 through 2003. The effort was led by the JGOFS North Pacific Synthesis Group, with the aim of quantifying CO₂ drawdown by physical and biological pumps in the North Pacific by identifying and studying the regional, seasonal to inter-annual variations in the key processes, and understanding their regulating mechanisms. Emphasis was placed on the similarities and differences of the biogeochemical regimes in the eastern and western subarctic Pacific. Effort was also made to address the future research directions which arose from the scientific findings during the North Pacific JGOFS process study. A brief overview of the papers from view points of CO₂ drawdown by physical and biological pumps, spatial variability, and temporal variability from seasonal to decadal scales is made, followed by suggestions for the directions of future research. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

The composition and distribution of saturated and aromatic hydrocarbons in nearshore sediments, river sediments, and coastal peat of the Alaskan Beaufort Sea: Implications for detecting anthropogenic hydrocarbon inputs     

Margarete S. Steinhauer  Paul D. Boehm   《Marine environmental research》1992,33(4)

A 3-year program, to determine spatial and temporal trends in sediment concentrations of hydrocarbons and metals from oil and gas exploration and development activities, was conducted in the US Beaufort Sea. Concentrations of saturated and aromatic hydrocarbons in sediments from the Beaufort Sea were elevated in comparison to non-polluted shelf-sediments from other regions of the US coast. Potential natural sources for hydrocarbons that were examined included riverine sediments and coastal peat. Significant quantities of fossil hydrocarbons characterize the surface sediments from the entire region. Sediment inputs from river discharges appear to account for this observation. The use of source-diagnostic ratios has allowed the differentiation of various sources in an area with high naturally-occurring hydrocarbon concentrations where effects due to oil and gas exploration and development activities may be obscured.  相似文献   

Laboratory measurements of uniform longshore currents: Reply to the comments of C.J. Galvin     

Paul J. Visser   《Coastal Engineering》1992,18(3-4)

  相似文献   

Interannual variability in Nordic seas primary production   总被引：1，自引：0，他引：1  

Skogen  Morten D.; Budgell  W. Paul; Rey  Francisco 《ICES Journal of Marine Science》2007,64(5):889-898

  相似文献   

Acoustic and stiffness properties of gillnets as they relate to small cetacean bycatch     

Mooney  T. Aran; Au  Whitlow W. L.; Nachtigall  Paul E.; Trippel  Edward A. 《ICES Journal of Marine Science》2007,64(7):1324-1332

  相似文献   

Simulating trawl herding in flatfish: the role of fish length in behaviour and swimming characteristics   总被引：2，自引：0，他引：2  

Winger  Paul D.; Walsh  Stephen J.; He  Pingguo; Brown  Joseph A. 《ICES Journal of Marine Science》2004,61(7):1179-1185

  相似文献   

Autonomous underwater vehicles: future platforms for fisheries acoustics   总被引：3，自引：1，他引：3  

Fernandes  Paul G; Stevenson  Pete; Brierley  Andrew S; Armstrong  Frederick; Simmonds  E.John 《ICES Journal of Marine Science》2003,60(3):684-691

  相似文献